Q.

[Co(NH3)6]3+ and [CoF6]3 Are respectively known as:

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a

Spin free Complex, Spin paired Complex

b

Spin paired Complex, Spin free Complex

c

Outer orbital Complex, Inner orbital Complex

d

Inner orbital Complex, Spin paired Complex

answer is B.

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Detailed Solution

[Co(NH3)6]3+
Co3+(strong field ligand)3d6(t2g6,eg0),
Hybridisation : d2sp3
Inner orbital complex(spin paired complex) pairing will take place.
[CoF6]3
Co3+(weak field ligand)3d6(t2g4,eg2)
Hybridisation : sp3d2
Outer orbital complex (spin free complex), no pairing will take place

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