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Q.

CoCl2+KNO2+CH3COOH[X]+H2O+KCl+CH3COOK+NO (Unbalanced equation).

Choose the correct statement about X.

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a

X is a yellow crystalline solid insoluble in water.

b

X is a green coloured compounds known as Rinman's green.

c

IUPAC name of X is potassium hexanitrito-N-cobaltate (II),

d

The compound X is an inner orbital complex.

answer is A, D.

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Detailed Solution

Here,

Co2++7NO2+2H++3K+K3CoNO26 Yellow ppt.+NO+H2O

                                                     (X) d2 sp3 (inner orbital complex)

Thus, X is a yellow crystalline solid insoluble in water and an inner orbital complex.

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