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Q.

Colour of KMnO4,K2CrO4,K2Cr2O7 is due to

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a

Unpaired electrons

b

Charge-transfer

c

d-d transitions

d

All of these

answer is B.

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Detailed Solution

 The number of unpaired electrons in KMn+7O4,K2Cr+6O4,K2Cr+62O7 respectively are 0,0,0.

Un paired electrons are not available, hence they should be color less, but they exhibit color property due to charge transfer between ligands and central metal.

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