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Q.

 

Column - I

(Ground state configuration)

 

Column – II

(Rule violated)

I
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AHund’s only
II
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BAufbau only
III
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CPauli only
IV
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DHund’s and Pauli’ only
V
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EHund’s and Aufbau only
  FAufbau, Hund’s and Pauli
  GNo rule violated

 

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a

I - C, II - E, III - B, IV - F, V - G

b

I - D, II - A, III - B, IV - F, V - G

c

I - C, II - E, III - B, IV - A, V - G

d

I - C, II - A, III - B, IV - D, V - G

answer is A.

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Detailed Solution

I) 1s - two electrons with parallel spin - Violation Pauli’s exclusion principle
II) In 2p - one of the half - filled degenerate orbital has opposite instead of parallel spin - Hund’s rule violated
III) Only Aufbau rule is violated
IV) Before filling 2s, electron entered into 2p - Aufbau rule violated
V) No rule is violated

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