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Q.

 Column I Column II
 Solubility is x M Ksp
ALi3K3[AlF6]2p108x5
BZirconium phosphateQ2916x8
CAntimony(III) sulphider27x4
DAluminium hydroxides6912x7
    

 

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a

A-s      B-p     C-r    D-q

b

A-s      B-p      C-q     D-r

c

A-p     B-s      C-r   D-q

d

A-q      B-t      C-p     D-r

answer is D.

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Detailed Solution

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  (aq)  LiK3(AIF6)23Li+3K+2(AIF6)3                                                           3x         3x                      3xKsp=333322x8=2916x8(bt)Zr3(PO4)43Zx+4+4PO43                                                  3x          4xKsp=3344x7=6916x7
  
(cp)Sb2S32Sb3++3S2                                      2x           3x(dr)AI(OH)3AI3++3OH                                               x           3xKsp=1133x4=27x4(es)CaF2Ca2++2F                                    x           3xKsp=1223x3=4x3

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