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Q.

 Column-I Column-II
A)Bp)+1.25 V (Eofor M3+/M)
B)Alq)303 K(m.p.)
C)Tlr)1.66 V (Eofor M3+/M)
D)Gas)801 kJ mol1(IE1)

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a

A-q; B-p; C-r; D-s 

b

A-r; B-q; C-s; D-p

c

A-p; B-s; C-q; D-r

d

A-s; B-r; C-p; D-q

answer is A.

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Detailed Solution

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The first ionization enthalpy of B is 801 kJ mol1,Eofor Al3+/Al is 1.66 V, Eo  for  Tl3+/Tl+is +1.25 V  and the m.p. of Ga is 303 K.

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