Q.

Column-I (compound) Column-II (Enol content)
A) CH3C||OOCH2CH3P) 80
B) PhC||OCH3Q) 89.2
C) CH3C||OCH2C||OCH3R) 1.1×106
D) PhC||OCH2C||OCH3S) 1.4

Choose the correct matching from the options given below 

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a

A – P, B – Q, C – R, D -S  

b

A – S, B –R, C – Q, D – P 

c

A – R, B – S, C – P, D - Q   

d

A – S, B – R, C – P, D – Q

answer is C.

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Detailed Solution

The increasing order of enol content is  
 Ketones < Ketoester < diketone < diketone with ‘ph’ group

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Column-I (compound) Column-II (Enol content)A) CH3−C||O−OCH2CH3P) 80B) Ph−C||O−CH3Q) 89.2C) CH3−C||O−CH2−C||O−CH3R) 1.1×10−6D) Ph−C||O−CH2−C||O−CH3S) 1.4Choose the correct matching from the options given below