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Q.

Column I (compound)

Column-II (pKb)

A) NH3

I) 4.75

B) CH3NH2

II) 3.38

Question Image
 III. 9.38

Identify the correct match from the following

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a

A-II,B-III,C-I

b

A-III,B-II,C-I

c

A-I, B-II,C-III

d

A-III,B-I,C-II     

answer is A.

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Detailed Solution

Question Image

Less is the pKb value, higher is the basic character. Aryl amine has highest pKb value (which means less basic) because the lone pair of electrons of N delocalized on the ring. After that pKb value of ammonia is higher than CH3-NH2 because of the presence of alkyl group, the basic strength of amines increased.

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