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Q.

Column – I : Formula with ratio of coordination number of cation to anion packing for the given closest 3D packing of anions with anion and anion are in contact
Column – II : Total number of voids of definite shape occupied per unit cell.
 

Column–I

Column–II

A)

MX2[6:3] (fcc)

P)

Half tetrahedral voids are occupied.

B)

MX[4:4] (hcp)

Q)

one third octahedral voids are occupied

C)

M2X3[6:4] (hcp)

R)

Half octahedral voids are occupied

D)

MX3[6:2] (hcp)

S)

Two thirds octahedral voids are occupied

 

 

T)

Size of the cation can be 0.414 times that of anion

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a

A–T, B–P, C–RT, D–Q

b

A–R, B–P, C–Q, D–T 

c

A–P, B–PT, C–ST, D–Q

d

A–RT, B–P, C–S, D–QT

answer is B.

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Detailed Solution

For fcc and hcp, with n spheres there are 2n tetrahedral voids and n octahedral voids

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