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Q.

 

Column I

(Benzene derivative)

 Column-II
(Electron migration effect observed)
I)
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a)+I, +hyperconjugation
II)
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b)-I, +M
III)
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c)-I, -M

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a

I- b,   II- a,  III- c 

b

I- b,  II- c,  III- a 

c

I- c,  II-  a,  III- b

d

I- a,  II- b ,  III- c

answer is C.

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Detailed Solution

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I) -NO2 group has a multiple bond between nitrogen and oxygen. It shows -I, -M effect.

II) -CH3 group is a +I group with three hyper conjugated H-atoms. It shows +I, +R effect.

III)  -NH2 group shows -I effect as it has nitrogen atom which is more electronegative than carbon.

      Since there is lone pair on nitrogen in conjugation with double bond of Benzene ring, it shows +M effect.

      Thus it shows -I, +M effect.

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