Q.

Column IColumn II
a- Fe2+p- Set of quantum no. for last e- is n=2,l=1 m=1,s=+12
b- Mn+4q- Magnetic moment (μ)= zero 
c-Zn+2r- Spin multiplicity (SM)=4
d-Na+s- Total no. of exchange pairs in 3d-subshell =10
 t-Paramagnetic species

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a

[a-s, t); (b-r, t), (c-q); (d- q)

b

[a-s); (b-r, t), (c-q); (d-p)

c

[a-s, t); (b-r, t), (c-q); (d-p, q)

d

[a-s, t); (b-r), (c-p); (d-p, q)

answer is A.

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Detailed Solution

For Fe2+ total no. of exchange pairs in 3d-subshell is equal to 10 and it is a Paramagnetic species.

For Mn+4the magnetic moment is equal to zero and its nature is  paramagnetic species.
For Zn+2 the magnetic moment is equal to zero

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