Q.

 Column-I Column-Ii
A)F-centersp)Extra cations present in interstitial sites
B)Metal excess defectq)Some cations are replaced with one of higher valence
C)Metal deficiency defectr)Both cations and anions are missing from lattices
D)Schottky defectss)Electrons trapped in anionic vacancies
 (A)(B)(C)(D)
1)spqr
2)pqsr
3)sqrp
4)pqrs

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a

2

b

1

c

3

d

4

answer is A.

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Detailed Solution

F – centre – Anionic vacancy
Metal excess – Extra cation
Metal deficiency – Cations replaced by high valency
Schottkey – Cations & anions missing

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