Column-IColumn-II(p) [Cr(H2O))6 ] Cl3(i) Interstitial water(q) BaCl2·2H2O(ii) Coordinated as well as hydrogen bonded H2O(r) [Cu(H2O4)]2+ SO42-·H2O(iii) Coordinated H2O

Column-IColumn-II(p) [Cr(H2O))6 ] Cl3co- ordinated H2O(q) BaCl2·2H2Ointerstitial water(r) [Cu(H2O4)]2+ SO42-·H2Oco -ordinated as well as hydrogen bonded H2O

Column-IColumn-II(p) [Cr(H2O))6 ] Cl3(i) Interstitial water(q) BaCl2·2H2O(ii) Coordinated as well as hydrogen bonded H2O(r) [Cu(H2O4)]2+ SO42-·H2O(iii) Coordinated H2O

Column-IColumn-II(p) [Cr(H2O))6 ] Cl3co- ordinated H2O(q) BaCl2·2H2Ointerstitial water(r) [Cu(H2O4)]2+ SO42-·H2Oco -ordinated as well as hydrogen bonded H2O

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Column-I Column-II
(p) [Cr(H₂O))₆ ] Cl₃ (i) Interstitial water
(q) ${BaCl}_{2} \cdot 2 H_{2} O$ (ii) Coordinated as well as hydrogen bonded H₂O
(r) [Cu(H₂O₄)]²⁺ ${SO}_{4}^{2 -} \cdot H_{2} O$ (iii) Coordinated H₂O

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(p) $\to$ (iii); (q) $\to$ (ii); (r) $\to$ (i)

(p) $\to$ (i); (q) $\to$ (ii); (r) $\to$ (iii)

(p) $\to$ (iii); (q) $\to$ (i); (r) $\to$ (ii)

(p) $\to$ (ii); (q) $\to$ (iii); (r) $\to$ (i)

answer is A.

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Detailed Solution

Column-I	Column-II
(p) [Cr(H₂O))₆ ] Cl₃	co- ordinated H₂O
(q) ${BaCl}_{2} \cdot 2 H_{2} O$	interstitial water
(r) [Cu(H₂O₄)]²⁺ ${SO}_{4}^{2 -} \cdot H_{2} O$	co -ordinated as well as hydrogen bonded H₂O