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Q.

Column II given isomerism for compounds given in Column I. Match them correctly.


Matrix:


 

Column I

 

Column II

(a)

(a) CH3COOH and HCOOCH3

(i)

Functional isomerism

(b)

(b) 1-butene and 2-butene

(ii)

Metamers

(c)

(c) diethyl ether and methyl propyl ether

(iii)

Position isomers

(d)

(d) dimethyl ether and ethanol

(iv)

Chain isomers


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a

a-iv; b-iii; c-ii; d-i

b

a-iii; b-ii; c-iv; d-i

c

a-i; b-iii; c-ii; d-iv

d

a-iv; b-ii; c-i; d-iii 

answer is A.

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Detailed Solution


Functional isomers are structural isomers that have the same chemical formula (the same number of atoms of the same elements), but the atoms are connected differently, resulting in dissimilar groupings. Metamers are isomers that share the same chemical formula but have distinct alkyl groups on both sides of functional groups. This isomerism phenomenon is known as metamerism. Positional isomers are molecules with the same chemical formula but distinct functional groups linked to the carbon chain. Chain isomers are molecules that have the same chemical formula but a distinct carbon skeleton.
 
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