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Q.

Column-I
(Reaction)
 

Column-II

(Slope in Ellingham
diagram)

 
I)C(s)+O2(g)CO2(g)A)Straight line parallel to
x-axis
II)2C(s)+O2(g)2CO (g)B)Negative slope
III)2CO(g)+O2(g)2CO2(g)C)Positive slope
IV)2Mg(s)+O2(g)2MgO(s)D)Straight line parallel to
y-axis

 

 

 

 

 

 

 

 

 

 

 

 

 

Graph is plotted between

Δf0G  of oxides (y-axis) vs temperature (x-axis)
The correct match between column-I and column -II is

 IIIIIIIV
1)ABCC
2)ABCD
3)ACBC
4)ABCB

 

see full answer

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a

1

b

2

c

3

d

4

answer is A.

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Detailed Solution

detailed_solution_thumbnail

ΔG=ΔHTΔS  l) ΔS=0,TΔS=0
Straight line  parallel to x-axis
 II) ΔS=+ve,TΔS=ve
Negative slope ( ΔG decreases with ‘T’)
 III) ΔS=ve,TΔS=+ve
Positive slope (ΔG increases with ‘T’)
IV) Positive slope ( ΔGincreases with ‘T’)

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