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Q.

Comment on the C-C bond length for C6H6 and C2F6 compounds.

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a

 dCC(C2H6 )>dCC(C2F6 )

b

 dCC(C2H6 )<dCC(C2F6 )

c

 dCC(C2F6 )=dCC(C2H6 )

d

Can’t be predicted 

answer is A.

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Detailed Solution

The structure of C2H6 is:

Question Image

The structure of C2F6 is:

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In C2H6, there is no electronegativity difference between C and H whereas in C2F6, there is electronegativity difference between C and F. As a result, partial positive charge is generates on both C atoms of C2F6. This results in shortening of C-C bond length of C2F6 so that the electrons between two carbon atoms becomes close and try to stabilize the positive charge on carbon atoms.

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Comment on the C-C bond length for C6H6 and C2F6 compounds.