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Q.

Complex of HgCo4SCN has two isomers X and Y. If both isomers give scarlet red ppt. with KI and magnetic moment (μ) of X>Y then, which of the following option is incorrect? 

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a

X and Y are different in structure

b

Oxidation of Hg and Co are same in both the complex

c

X has Δ0<P

d

both have same hybridisation.

answer is D.

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Detailed Solution

Since both isomers has sp3 hybridizationComplex of HgCo4SCN has two isomers are Hg+2CO+2Co(SCN)4 and  +2CO+2o(NCS)4 They give scarlet red ppt. with Kl and magnetic moment (μ) of X>Y then both have same hybridization.

Hence, option D is correct.

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