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Q.

Complex X of composition Cr(H2O)6Cln has a spin only magnetic moment of 3.83 BM. It reacts with AgNO3 and shows geometrical isomerism. The IUPAC name of X is:

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a

Tetraaquadichlorido chromium (III) chloride dihydrate

b

Tetraaquadichlorido chromium (IV) chloride dihydrate

c

Hexaaqua chromium (III) chloride

d

Dichloridotetraaqua chromium (IV) chloride dihydrate 

answer is D.

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Detailed Solution

 μ=n(n+2)B.M=3.83B.M. n=3(n=No.ofunpairede)
Therefore, oxidation number of Cr should be+3.
Hence complex is  Cr(H2O)6Cl3
Complex shows geometrical isomerism, therefore formula of complex is  [Cr(H2O)4Cl2]Cl.2H2O
IUPAC Name : Tetraaquadichlorido chromium (III) chloride dihydrate

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