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Q.

Composition of sample of wurtzite is  Fe0.93O1.0 what percentage of iron is present in the form of Fe (III)? 

 

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Detailed Solution

In pure form, FeO has Fe2+ and O2- which present in 1:1 ratio. According to given formula, number of Fe2+ has 0.93, which means that 0.07 number of Fe2+ are missing. Missing charge due to 0.07 of Fe2+ is calculated as:

0.07×2=0.14

Equal number of Fe2+ ions have been replaced by equal number of Fe3+ ions. 

In the given formula, 0.93 Fe2+ ions have 0.14 Fe3+ ions

100 Fe2+ ions=0.93 Fe2++ 0.14 Fe3+=0.140.93×100=15.05%

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