Q.

Compound (A) does not react with Tollens or Grignard reagent, but after treatment with NaNH2, it gives the above test. The compound (A) is/are:

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a

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b

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c

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d

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answer is , C, D.

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Detailed Solution

Internal alkyne on reaction with NaNH2 isomerises to terminal alkyne, which gives all the tests mentioned. Here (1), (3), and (4) are internal alkynes.

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