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Q.

Compound A (molecular formula C3H8O) is treated with acidified potassium dichromate to form a product B (molecular formula C3H6O). B forms a shining silver mirror on warming with ammonical silver nitrate. B when treated with an aqueous solution of H2NCONHNH2.  HCI and sodium acetate gives a product C. Identify the structure of C.

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a

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b

CH3CH2CH=NCONHNH2

c

CH3CH2CH=NNHCONH2

d

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answer is A.

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Detailed Solution

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Reaction of B indicates that B is an aldehyde thus B should be C2H5CHO or CH3CH2CHO and therefore C should be
CH3CH2CH=NNHCONH2.

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Compound A (molecular formula C3H8O) is treated with acidified potassium dichromate to form a product B (molecular formula C3H6O). B forms a shining silver mirror on warming with ammonical silver nitrate. B when treated with an aqueous solution of H2NCONHNH2.  HCI and sodium acetate gives a product C. Identify the structure of C.