Q.

Compound A reacts with PCl5 to give B which on treatment with KCN followed by hydrolysis gave propionic acid. What are A & B respectively ?

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a

C2H5OH & C2H5Cl

b

C2H6 & C2H5Cl

c

C2H5OH & C2H4Cl2

d

C3H8 & C3H7Cl

answer is D.

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Detailed Solution

After reacting a compound "A" with phosphorus pentachloride PCl5, a compound "B" an alkyl halide is formed, which then reacts with KCN to form cyanide, which then hydrolyzes to form acid. The reaction:

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A naturally occurring carboxylic acid called propionic acid has an unpleasant odor and is colorless and corrosive in its pure form.

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