Compound (A) $C_{8} H_{9} Br,$ gives a white precipitate when warmed with alcoholic ${AgNO}_{3}$ . Oxidation of (A) gives an acid (B), $C_{8} H_{6} O_{4}$ . (B) easily forms anhydride on heating. Indentify the compound (A).

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answer is D.

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Detailed Solution

Aliphatic Br gives precipitate with ${AgNO}_{3}$ .The Oxidation of $- {CH}_{2} Br$ gives $- COOH$ and also $- {CH}_{3}$ gives $- COOH$ . The two $- COOH$ group must be in ortho positions to give anhydride. Hence,

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