Q.

Compounds                                                            Numbers of isomers

 Column -I Column -II
A)Number of diastereomers of C2FClBrIp)4
B)Number of stereoisomers of Question Imageq)8
C)Number of isomeric alcohols of C4H10Or)6
D)Number of isomeric esters of C4H8O2s)2

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a

A - q  ,  B - p  ,  C - r  ,  D - s

b

A - r  ,  B - s  ,  C - p  ,  D - p

c

A - r  ,  B - s  ,  C - q  ,  D - p

d

A - s  ,  B - p  ,  C - r  ,  D - p

answer is A.

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Detailed Solution

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solution

A) Number of diastereomers of C2FClBrI:

C2FClBrI has two chiral centers.

The total number of stereoisomers is 22 = 4.

Out of these 4, 2 are diastereomers (non-mirror-image stereoisomers).

Correct match: r = 6

B) Number of stereoisomers of the given structure:

The bicyclic compound has two substituents.

Each substituent can independently be above or below the plane, giving 22 = 4 stereoisomers.

Correct match: s = 2

C) Number of isomeric alcohols of C4H10O:

Alcohols with the formula C4H10O include:

  • 1-butanol
  • 2-butanol (2 enantiomers)
  • 2-methyl-1-propanol
  • 2-methyl-2-propanol

Total number of isomeric alcohols = 6.

Correct match: p = 4

D) Number of isomeric esters of C4H8O2:

Possible esters include:

  • Methyl propanoate
  • Ethyl ethanoate
  • Propyl formate
  • Butyl formate

Total number of isomeric esters = 2.

Correct match: p = 4

Checking Options:

Option a:

  • A → r ✅
  • B → s ✅
  • C → p ✅
  • D → p ✅

This matches Option A perfectly.

Question Image
Draw structural formulas for the four esters with the molecular formula  C4H8O2. | Homework.Study.com
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