Compounds X and Y are obtained by the reaction of ${Cl}_{2}$ with cold and dilute solution of NaOH and compounds X and Z are formed with hot and concentrated solution of NaOH. The compounds Y and Z respectively are

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NaClO,HCl

NaCl, ${NaClO}_{3}$

NaCl,NaClO

NaClO, ${NaClO}_{3}$

answer is C.

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Detailed Solution

Dilute NaoH react with chlorine to give NaCl and NaOCl but concentrated NaOH react with Chlorine to give NaCl and ${NaClO}_{3}$

$2 N a O H + C l_{2} \to N a C l (X) + N a C l O (Y) + H_{2} O$

$6 N a O H + 3 C l_{2} \to 5 N a C l + N a C l O_{3} (Z) + 3 H_{2} O$

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