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Q.

Compounds X and Y give effervescence with $N a H C O_{3}$ solution, X gives a silver mirror with ammonical $A g N O_{3},$ while Y gives a sweet smelling compound on heating with alcohol in the presence of $H_{2} S O_{4}$ : X and Y are

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a

$H C O O H a n d C H_{3} C O O H$

b

$C H_{3} C O C H_{3} a n d H C O O H$

c

$C H_{3} C H O a n d C H_{3} C O O H$

d

$C H_{3} C O O H a n d C H_{3} C O C H_{3}$

answer is A.

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Detailed Solution

Formic acid can reduce Tollens reagent but not acetic acid. All carboxylic acids liberates $C O_{2}$ from ${NaHCO}_{3}$

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Compounds X and Y give effervescence with NaHCO3 solution, X gives a silver mirror with ammonical AgNO3, while Y gives a sweet smelling compound on heating with alcohol in the presence of H2SO4 : X and Y are