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Q.

Compressibility factor of a gas is given by the equation Z=PVnRT. On this basis, mark the correct statement.

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a

When Z > 1, real gases get compressed easily.

b

When Z = 1, real gases are difficult to compress.

c

When Z = 1 real gases get compressed easily.

d

When Z > 1, real gases are difficult to compress.

answer is C.

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Detailed Solution

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  • Compressibility factor of a gas is given by,
    Z=PVnRT
  • For ideal gas, PV = nRT
  • Hence the value of compressibility factor Z will be equal to 1.
  • For real gases the equation, PV = nRT cannot be true. 
  • Hence Z cannot be equal to one. Z for real gases will be less than one or greater than one.
  • When Z<1, the gas becomes more compressible and when Z>1, the gas becomes less compressible.
  • Let us look into the options given.
  • Option a says that when Z>1, real gases get compressed easily. This statement is wrong as we discussed. 
  • When Z>1, real gases are easy to compress. Because at this condition the molecular attraction dominates which favours compression. Hence Option a is wrong.
  • Option b says that when Z=1, real gases get compressed easily. 
  • For real gases Z is not equal to one. Hence this statement is wrong.
  • Option c says that when Z>1, real gases are difficult to compress. This statement is correct.
  • When Z>1, the gas becomes less compressible. The reason for this is that when Z>1, the forces of attraction between the molecules is weak. 
  • The attraction should be strong for compression to happen.
  • Option d says that when Z=1, real gases are difficult to compress. 
  • Real gases cannot have the value of Z as one. Hence this statement is also wrong.
  • Hence the correct option is C.
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