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Q.

Conc. HNO₃ oxidises I₂ & P₄ respectively to

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a

${HIO}_{4}, H_{3} {PO}_{3}$

b

${HIO}_{4}, H_{3} {PO}_{4}$

c

${HIO}_{3}, H_{3} {PO}_{4}$

d

$HI, H_{3} {PO}_{3}$

answer is B.

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Detailed Solution

Iodine reacts with concentrated nitric acid according to the following equation:

10HNO₃+I₂⟶2HIO₃+10NO₂+4H₂O

P₄ + HNO₃ → H₃PO₄ + NO₂ + H₂O.

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Conc. HNO3 oxidises I2 & P4 respectively to