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Q.

Concentrated HCl, HNO3, and a 3:1 combination of concentrated HCl and HNO3 were taken in separate tubes marked A, B, and C, respectively. In each test tube, a little bit of metal was placed. In test tubes A and B, nothing changed; nevertheless, the metal dissolved in test tube C. The metal could be __________________.

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a

Au 

b

Al

c

Cu

d

Al 

answer is B.

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Detailed Solution

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The metal could be Au, Pt.
According to the question, the mixture to test the metals in test tubes A, B, and C is aqua regia. Gold(Au) and platinum(Pt) can be dissolved using a solution of three parts concentrated hydrochloric acid and one part concentrated nitric acid (Aqua regia - 3:1 ratio).
Platinum(Pt) and gold(Au) can only dissolve in aqua regia; they cannot dissolve in weak acids.
 

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