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Q.

Concentration of H2SO4 and K2SO4 in a solution is 0.1 M and 2×103M respectively. Molar solubility of BaSO4 in the same solution is X×10Y M (expressed in scientific notation). The value of Y is ______.
[Given: Ksp(BaSO4)=3.0×1010;Ka1(H2SO4)=very large; Ka2(H2SO4)=1.2×102  ]
 

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Detailed Solution

HSO4 H++    SO420.1               0.1         2×1030.1x         0.1+x   2×103+x1.2×102=(0.1+x)( 2×103+x)(0.1x)x1.35×102BaSO4(s) Ba2++SO42                           s         1.55×102+s                           s         1.55×102[s is neglegible]1.55×102s=3×1010s=1.9×108

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