Q.

Consider 0.1M solutions of two solutes X and Y. The solute X behaves as a univalent electrolyte while the solute Y dimerises in solution. Which of the following statements is/are correct?
I. The boiling point of the solution of X will be higher than that of Y
II. The osmotic pressure of solution Y will be lower than that of X
III. The freezing point of solution X will be lower than that of Y
IV. The RLVP of both the solutions will be the same
Select the correct answer from the option

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a

I, III and IV

b

I, II and III

c

II, III and IV

d

I, II and IV

answer is A.

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Detailed Solution

Colligative properties depend on the number of solute particles and not on the nature of the solution. The lesser the number of solute particles, the less will be the colligative properties. Hence, option one is correct.

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