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Q.

Consider a mass  m=15gm of nitrogen enclosed in a vessel at temperature  T=300K.   The amount of heat required to double the root mean square velocity of its molecules  nearest integer N in 10N  Joules is

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answer is 4.

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Detailed Solution

All the diatomic gases (H2,O2,N2,etc.)  exhibit 5 degrees of freedom between 
100 – 1000 K, 3 of translation and 2 of rotation. Hence, internal energy of n  moles of N2  at T = 300 K would be U=52nRT
Translational kinetic energy of each molecule is
 12mavrms2=32kT 
where ma   is the mass of the molecule.
If rms speed increases α  times, v'rms=αvrms , then temperature has to be raised to T'  such that
12mav'rms2=32kT'  
or  T'=α2T
The internal energy therefore increases to
U'=52nRT'  
Change in internal energy,
 ΔU=U'U=52nR(T'T) =52nRT(α21) =52mMRT(α21) 
where the number of moles n=mM ,  m is the mass of gas and M is its molecular weight.
On substituting numerical values, m=15g , T=300K ,α=2   and M=28g/mol for  N2, we get U=52×1528×8.31×300×(41)J=104J

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