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Q.

Consider a solution of pH = 6
Case-I : It is diluted by 100 times
Case-II : Hydronium concentration is decreased by 100 times.
If all the measurements are made at 298K, then the correct statement is

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a

pH in both cases will be greater than 7

b

pH in (I) will be greater than 7 but in (II) will be lesser than 7

c

pH in (I) will be lesser than 7 but in (II) will be greater than 7

d

pH in both cases will be lesser than 7

answer is C.

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Detailed Solution

I) Dilution can never change the medium
[H3O+] of solution =10-8 M
[H3O+] of  H2O=107M
Net[H3O+]=(108+107)=1.1×107

pH=7log1.1=6.956
II) Decrease in  [H3O+] can be achieved by adding alkali also, medium can change 

[H3O+]=108 

pH=8

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