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Q.

Consider a titration of potassium dichromate solution with acidified Mohr's salt solution using diphenylamine as indicator. The number of moles of Mohr's salt required per mole of dichromate is

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a

6

b

3

c

4

d

5

answer is D.

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Detailed Solution

6Fe2++Cr2O72-+14H+6Fe3++2Cr3++7H2O

                      Cr2O72-2Cr3+

x-factor = 6

 Mohr's salts FeSO4·NH42SO4·6H2O

 Oxidation, Fe2+Fe3+

x-factor = l mole ratio is reverse of x-factor ratio.

Therefore, one mole of dichromate required = 6moles of Mohr's salt.

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