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Q.

Consider an hypothetical electrochemical cell :
A(s)A(aq)2+B(aq)2+B(s)
The standard emf of the given cell at 25oC and 20oC are 0.3525 V and 0.3533 V
respectively. The value of magnitude ΔSo for the cell in (J/K) is ________.

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answer is 30.88.

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Detailed Solution

E250C0=0.3525V E200C0=0.3523VdEdT=E0250CE200C0T1T2=0.35250.3533(2520)dEdT=1.6×104 volt /KΔS0=nFdEdT=2×96500×1.6×104J/K ΔS0=30.88J/K

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