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Q.

Consider one He+ ion in excited state (n = 5). Which of the following observations will hold true as per the Bohr's model

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a

10 emission spectral lines will be seen

b

The ionisation energy needed is less than 2eV

c

The longest emitted wavelength is less than 10/R (R = Rydberg's constant)

d

The electronic separation from the center of nucleus is more than 6 Ao

answer is D.

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Detailed Solution

A multitude of He+ will produce 10 possible emission lines.

A single He+ can produce maximum 4 lines (not more)

5 4 3 2 1En=13.6z2n2=13.6×  2252=13.6×425=2.176  eVIE=+2.176  eV  >  2eV1λ=  RZ2  1n121n221λ=  R.41421521λ=  4R916×251λ=16×254×9×R=1009R>  10Rrn=0.53  ×  n2Z=  0.53  ×52Z=6.625  Ao>  6Ao

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