Q.

Consider separate solutions of 0.500MC2H5OH(aq),0.100MMg3PO42(aq),0.250MKBr(aq) and 0.125 MNa3PO4(aq) at 50C. Which statement is true about these solutions, assuming all salts to be strong electrolytes?

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a

 0.125MNa3PO4(aq) has the highest osmotic pressure

b

0.500MC2H5OH(aq) has the highest osmotic pressure.

c

They all have the same osmotic pressure

d

0.100MMg3PO42(aq) has the highest osmotic pressure

answer is B.

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Detailed Solution

All the four solutions have the same amount of the species present in the solution.

C2H5OH                             0.500M0.100MMg3PO4                 0.300MMg2++0.200PO430.250MKBr                           0.250MK++0.250MBr0.125MNa3PO4                    0.375MNa++0.125MPO43

Since all of them have the concentration of total species, their osmotic pressure will have the same value.

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