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Q.

Consider that a d6 metal ion M2+ forms a complex with aqua ligands, and the spin only magnetic moment of the complex is 4.90BM. The geometry and the crystal field stabilization energy of the complex is?

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a

octahedral and 24Δ0+2P

b

octahedral and 1.6Δ0

c

tetrahedral and 0.6Δt

d

tetrahedral and1.6Δt+1P

answer is C.

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Detailed Solution

The metal ion  M2+ with d6 configuration with aqua ligands will have t2g4eg2 in octahedral field and eg3t2g3 in tetrahedral. Then crystal field stabilization energy in octahedral field will be 0.4×4+0.6×2+PΔ0 and in tetrahedral field0.6×3+(0.4×3)+PΔt. The tetrahedral value is 0.6Δt+p; the value match with 3

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