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Q.

Consider the complex given below NH35RuIIN2RuIINH354+and the statements regarding it.

(i) N-N bond length is longer than that in free N2 molecule. 

(ii) It is diamagnetic having t24eg2 configuration of each Ru2+ ion.

(iii) Back-bonding is involved in this.

The correct statement(s) is/are: 

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a

only (i)

b

only (i) and (iii)

c

only (ii) and (iii)

d

 all of these.

answer is B.

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Detailed Solution

NH35RuIIN2RuIINH354+ and the statements regarding it is diamagnetic having t24eg2 configuration of each Ru2+ ion.
Here, the statement (ii) is incorrect while other statements are correct.
(ii) diamagnetic ⇒ t24eg2.
Hence correct option B.

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