Consider the compounds given below :
$(I) {BiCl}_{3}, (II) {SbCl}_{3}, (III) {VCl}_{5}, (IV) {AlCl}_{3}$
Which would form oxo ion of $M O^{+}$ type when subjected to hydrolysis?

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$I, II, III$ only

$I, II, III, IV$

$I, II$ only

$I, II, IV$ only

answer is C.

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Detailed Solution

$(i) {BiCl}_{3} + H_{2} O \to BiOCl + 2 HCl (ii) {SbCl}_{3} + H_{2} O \to SbOCl + 2 HCl (iii) {VCl}_{5} + 2 H_{2} O \to {VO}_{2} Cl + 4 HCl (iv) {AlCl}_{3} + 3 H_{2} O \to Al {(OH)}_{3} + 3 HCl$

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