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Q.

Consider the compounds of Column-I  for electrophilic substitution reaction with Cl2 in presence of AlCl3 Match them with the nature of reaction and product formed from the Column-II

Colum-I                                                              Colum-II

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a

i-p;ii-q;iii-r;iv-s

b

i-s;ii-r;iii-q;iv-p

c

i-r;ii-q;iii-p;iv-r,s

d

i-r;ii-s;iii-q;iv-p

answer is C.

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Detailed Solution

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-Cl is an ortho para directing group and a ring deactivating group for benzene towards electrophilic substitution.

-CF3 is a meta directing group and a ring deactivating group for benzene towards electrophilic substitution.

-OMe is an ortho para directing group and a ring activating group for benzene towards electrophilic substitution. 

-NO is ring deactivating group for benzene towards electrophilic substitution. 

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