Consider the following complex ions/compounds:
(i) $[P t C l_{2} {(N H_{3})}_{2}]$ (ii) $[C o C l_{3} {(N H_{3})}_{3}]$ (iii) $[P t C l_{2} (e n)]$
(iv) ${[C r B r_{2} {(e n)}_{2}]}^{+}$ (v) ${[R h {(e n)}_{3}]}^{3 +}$ (vi) ${[C o C l_{2} B r_{2}]}^{2 -}$
Then calculate the sum of total number of geometrical isomers in all above complexes?

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answer is 6.

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Detailed Solution

${[C o C l_{2} B r_{2}]}^{2 -}$ : tetrahedral complex
${[R h {(e n)}_{3}]}^{3 +}$ : does not exhibit geometrical isomerism
$[P t C l_{2} (e n)]$ : does not exhibit geometrical isomerism

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