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Q.

Consider the following complex ions
 P=[FeF6]3         Q=[V(H2O)6]2+           R=[Fe(H2O)6]2+
The correct order of the complex ions, according to their spin only magnetic moment values in (B.M) is 

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a

P<Q<R

b

R<P<Q

c

Q<R<P

d

Q<P<R

answer is C.

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Detailed Solution

 [FeFi]3:Fe+3(Ar)3d5
 
 F: Weak field ligand             Question Image
No.of unpaired  C=5
 μ=55+2          μ=35B.M       [V(H2C)6]+2  :V+2  :3d3

Question Image

No.of unpaired  e=3
 μ=3(3+2)       μ=15B:M          [Fe(H2O)6]+2Fe+2 :3d6
H2O:  Weak field ligand 
No.of unpaired e=4

Question Image

μ=4(4+2)         μ=24B.M

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