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Q.

Consider the following complex ions
 P=[FeF6]3 Q=[V(H2O)6]2+ R=[Fe(H2O)6]2+
The correct order of the complex ions, according to their spin only magnetic moment values (in B.M.) is :

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a

R < Q < P

b

R < P< Q

c

Q < R < P

d

Q < P < R

answer is C.

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Detailed Solution

[FeF6]3:Fe+3:[Ar]3d5
F : Weak field Ligand Question Image
No. of unpaired electron's = 5 
 μ=5(5+2) μ=35BM [V(H2O)6]+2:V+2:3d3

Question Image
No. of unpaired electron's = 3
 μ=3(3+2) μ=15BM [Fe(H2O)6]+2:Fe+2:3d6
H2O:Weak field Ligand Question Image

No. of unpaired electron's = 4
 μ=4(4+2) μ=24BM

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Consider the following complex ions P=[FeF6]3− Q=[V(H2O)6]2+ R=[Fe(H2O)6]2+The correct order of the complex ions, according to their spin only magnetic moment values (in B.M.) is :