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Q.

Consider the following complexes 

1) K2PtCl6        2) PtCl4.2NH3  3) PtCl4.3NH3  4) PtCl4.5NH3
Their electrical conductance in aqueous solutions are

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a

256, 0, 97 and 404 respectively

b

404, 0, 97 and 256 respectively

c

256, 97, 0 and 404 respectively

d

404, 97, 256 and 0 respectively

answer is A.

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Detailed Solution

coordination number of Pt is 6. Hence on aqueous solution the number of dissociated ions will be
I K2[PtCl6] − 3 ions
II [Pt(NH3)2Cl4] − 0 ions
III [Pt(NH3)3Cl3]Cl− 2 ions
IV [Pt(NH3)5Cl]Cl3 − 4 ions
More is the number of ions, more is the electrical conductance.

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