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Q.

Consider the following complexes

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Their electrical conductance in aqueous solutions are
 

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a

404, 0, 97 and 256 respectively
 

b

 256, 0, 97 and 404 respectively
 

c

 256, 97, 0 and 404 respectively
 

d

 404, 97, 256 and 0 respectively

answer is A.

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Detailed Solution

Conductance is directly proportional to number of ions.

thus, the higher the number of ions the higher will be the conductance.

In K2[PtCl6]  2K++[PtCl6]2-  there are 3 ions.

In PtCl4.2NH3    [Pt(NH3)2Cl4] there are no ions.

In [Pt(NH3)5Cl]Cl3 has 2 ions.

In [Pt(NH3)5Cl]Cl3 has 4 ions.

Hence, the correct option is option (A) 256, 0, 97 and 404 respectively.

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