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Q.

Consider the following compounds and the nitrogen atoms labelled from I to VIII.
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Choose the correct statement(s) from the following:

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a

If an equimolar mixture of all these three compounds is treated with HCl, V gets protonated first.

b

Basic character of I, II and III follow the order II>I>III

c

The lower basic nature of VIII compared to VII can be attributed to involvement of lone pair on VIII in aromatic stabilization.

d

Basic character of I, V and VII will almost be equal as all them are sp2  hybridized.

answer is A, B, C.

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Detailed Solution

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A) V is the most basic nitrogen of all the labelled nitrogen atoms.
B) III is in conjugation with the ring. I is sp2  hybridized while II is sp3  hybridized.
C) Self-explanatory
D) V is more basic than I and VII.

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