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Q.

Consider the following compounds :

 (P) ClF3     (Q) BrF3

The order of the angles between axial and equatorial bond pairs is :

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a

P<Q

b

P=Q

c

P>Q

d

None of these

answer is A.

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Detailed Solution

The order of the angles between axial and equatorial bond pairs is Chlorine trifluoride >Bromine trifluoride compounds
Chlorine trifluoride has a trigonal bipyramidal molecular structure with a 175° F-Cl-F bond angle.
The angle created by axial fluorine and equatorial fluorine is 86.2°.
As size of " C.A.个,B.A."↓
Thus, P > Q
Hence correct option is A.

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