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Q.

Consider the following conversions
i) O(g) +e- → O(g)-H1
ii) F(g) +e- → F(g)-H2
iii) Cl(g) +e- → Cl(g)-H3
iv) Na(g) → Na(g)+.H4
Incorrect statement is

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a

H2 is more negative than H1

b

H1H2 and  H3 are negative while  H4 is positive

c

H1 and H2 is less negative than H3

d

H2H3 are negative while  H1 is positive

answer is C.

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Detailed Solution

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O(g) + e- → O-(g)  is exothermic
F(g) + e- → F-(g)   is exothermic
Cl(g) + e- → Cl-(g) is exothermic
Na(g)  → Na+(g)     is endothermic.
ΔH1 , ΔH2 and ΔH3 are negative where as  ΔH4 is positive
Thus 3rd option is incorrect.

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