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Q.

Consider the following data
Heat of combustion of H2(g) = -241.8kJ mol-1
Heat of combustion of C(S) = -393.5kJ mol-1
Heat of combustion of C2H5OH(l) = -1234.7kJ mol-1
The heat of formation of C2H5OH(l) is(-) _________ kJ mol-1(Nearest integer)

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answer is 278.

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Detailed Solution

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H2+O2H2O() ; ΔHfo=241.8kJ/ mole C+O2CO2 ; ΔHfo=393.5kJ/ mole  C2H5OH+3O22CO2+3H2O ΔHcoms C2H5OH=2×ΔHf0CO2+3×ΔHfoH2OΔHfoC2H5OH
1234.7=2×393.5+3×241.8ΔHf0C2H5OH1234.7=787725.4ΔHf0C2H5OH1234.7+1512.4=ΔHf0C2H5OH277.7=ΔHf0C2H5OH5ΔHfoC2H5OH=278kJ/ mole 

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